[1,3-Bis(2,4,6-Trimethylphenyl)-2-Imidazolidinylidene]Dichloro-(3-Phenyl-1H-Inden-1-Ylidene)(Pyridyl)Ruthenium (Ii) - Names and Identifiers
Name | 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE]DICHLORO-(3-PHENYL-1H-INDEN-1-YLIDENE)(PYRIDYL)RUTHENIUM(II)
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Synonyms | UMICORE M31 [RuCl2(3-phenylinden-1-ylidene)-(pyridine)(N,N'-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene)] Dichloro(1,3-dimesitylimidazolidin-2-ylidene)(3-phenyl-1H-inden-1-ylidene)(pyridin-2-yl)ruthenate(II) Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](3-phenyl-1H-inden-1-ylidene)(pyridyl)ruthenium(II) 1,3-BIS(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE]DICHLORO-(3-PHENYL-1H-INDEN-1-YLIDENE)(PYRIDYL)RUTHENIUM(II) [1,3-Bis(2,4,6-Trimethylphenyl)-2-Imidazolidinylidene]Dichloro-(3-Phenyl-1H-Inden-1-Ylidene)(Pyridyl)Ruthenium (Ii)
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CAS | 1031262-76-6
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[1,3-Bis(2,4,6-Trimethylphenyl)-2-Imidazolidinylidene]Dichloro-(3-Phenyl-1H-Inden-1-Ylidene)(Pyridyl)Ruthenium (Ii) - Physico-chemical Properties
Molecular Formula | C41H41Cl2N3Ru
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Molar Mass | 747.77 |
Storage Condition | 2-8°C |
[1,3-Bis(2,4,6-Trimethylphenyl)-2-Imidazolidinylidene]Dichloro-(3-Phenyl-1H-Inden-1-Ylidene)(Pyridyl)Ruthenium (Ii) - Risk and Safety
Hazard Symbols | Xn - Harmful
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Risk Codes | R20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R36/38 - Irritating to eyes and skin.
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Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37 - Wear suitable protective clothing and gloves.
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WGK Germany | 3 |
[1,3-Bis(2,4,6-Trimethylphenyl)-2-Imidazolidinylidene]Dichloro-(3-Phenyl-1H-Inden-1-Ylidene)(Pyridyl)Ruthenium (Ii) - Introduction
[1,3-Bis (2,4, 6-trimethylphenyl)-2-imidazolidinylidene] (3-phenyl-1H-inden-1-ylidene) (pyridyl) ruthenium dichloride is a metal-organic compound with the molecular formula C62H55Cl2N4Ru. The following is a description of its nature, use, preparation and safety information:
1. nature:
-Appearance: Colorless to yellowish crystalline powder.
-Melting point: about 180-190°C.
-Solubility: Soluble in some organic solvents (such as chloroform, dichloromethane).
2. use:
-[1,3-Bis (2,4, 6-trimethylphenyl)-2-imidazolidinylidene] (3-phenyl-1H-inden-1-ylidene) (pyridyl) Ruthenium dichloride is a coordination ligand commonly used in organometallic catalytic reactions, such as olefin transfer hydrogenation, hydrogenation and disproportionation reactions.
3. Preparation method:
The synthesis of-[1,3-bis (2,4, 6-trimethylphenyl)-2-imidazolidinylidene] (3-phenyl-1H-inden-1-ylidene) (pyridyl) ruthenium dichloride generally requires an organometallic chemical reaction. A common method is to react the desired ligand with a metal precursor of [1,3-bis (2,4, 6-trimethylphenyl)-2-imidazolidylidene] (3-phenyl-1H-inden-1-ylidene) (pyridyl) ruthenium dichloride, and then purify the product by appropriate column chromatography or crystallization.
4. Safety Information:
-[1,3-Bis (2,4, 6-trimethylphenyl)-2-imidazolidinylidene] (3-phenyl-1H-inden-1-ylidene) (pyridyl) ruthenium dichloride is a chemical that requires safe handling precautions to avoid contact with skin and inhalation of powder or vapours. It is recommended to operate in a well-ventilated laboratory and wear appropriate protective gloves and goggles. For detailed safety information, refer to the safety data sheet of the compound.
Last Update:2024-04-10 22:29:15